Putting k=0 in the equation of electrodiffusion we neglect the electrostatic term. It leads to the following equation describing diffusion in ℜn [1, 2]
where D denotes a diffusion coefficient. This kind of equation represents an initial value problem. Assuming that the considered domain Ω in ℜ3 is of a cubic type [xmin, xmax]✗[ymin, ymax]✗[zmin, zmax] let us take u = 0 as a boundary condition. Now we seek a solution of the equation which satisfies this boundary condition and prescribed initial condition at the time t = 0. The solution of the equation is approximated by the triple sum
∞ | ∞ | ∞ | ||
u(x,y,z,t) = | ∑ | ∑ | ∑ | v0, kx, ky, kz e-(kx2 + ky2 + kz2)Dt sin(kxx) sin(kyy) sin(kzz), |
kx = 1 | ky = 1 | kz = 1 |
where v0, kx, ky, kz are unknown coefficients that must be determinated from the initial condition:
∞ | ∞ | ∞ | ||
g = u(., 0) = | ∑ | ∑ | ∑ | v0, kx, ky, kz sin(kxx) sin(kyy) sin(kzz). |
kx = 1 | ky = 1 | kz = 1 |
In the case of the domain being [0 π] ✗ [0 π] ✗ [0 π] and g = const the solution has the form
∞ | ||
u(x,y,z,t) = 64g/(π3) | ∑ | e-(kx2 + ky2 + kz2)Dt sin(kxx) sin(kyy) sin(kzz)/(kx ky kz). |
kx, ky, kz = 1, 3, … |
In the case of cylindrical domain defined by r ∈ [0, r0], θ ∈ [0, 2π) and z ∈ [0, π], and with the boundary condition of the form u = 0 the solution of diffusion equation can be expanded in an absolutely and uniformly convergent series of the form
∞ | ∞ | ||||||
u(r, θ, z, t) = | ∑ | ∑ | Jn(kn, mr/r0) | ( | an, mcos(n θ) + bn, m sin(nθ) | ) | sin(kz z)✗ |
n = 0 | m, kz = 1 |
✗ | e-((kn,m/r0)2 + kz2)Dt |
where kn, m are the zeros of the Bessel functions and an, m, bn, m are constants that must be found from the initial condition by making use of the orthogonality relation for the trigonometric and Bessel functions.